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Journal Articles

Determination of alkali and alkaline earth elements in radioactive waste generated from reprocessing plant by liquid electrode plasma optical emission spectrometry

Yamamoto, Masahiko; Do, V. K.; Taguchi, Shigeo; Kuno, Takehiko; Takamura, Yuzuru*

Journal of Radioanalytical and Nuclear Chemistry, 327(1), p.433 - 444, 2021/01

 Times Cited Count:0 Percentile:0.01(Chemistry, Analytical)

A simple, practical, and reliable analytical method for determination of Na, K, Ca, Sr, and Ba by liquid electrode plasma optical emission spectrometry is developed. Appropriate emission lines for quantification, interferences from co-existing elements, and effect of measurement conditions with cell damage have been investigated. The spike and recovery tests using actual sample have been performed for method validation, and negligible sample matrix effect has been observed. Consequently, the method is successfully applied to several radioactive wastes. The obtained data have been agreed well with data from computer calculation and inductively coupled plasma optical emission spectrometry within 10% difference.

Journal Articles

Development of profile monitors on target for high-intensity proton accelerators

Meigo, Shinichiro; Takei, Hayanori; Matsuda, Hiroki; Yuri, Yosuke*; Yuyama, Takahiro*

Proceedings of 16th Annual Meeting of Particle Accelerator Society of Japan (Internet), p.515 - 519, 2019/07

no abstracts in English

Journal Articles

A New measuring method for elemental ratio and Vickers hardness of metal-oxide-boride materials based on Laser-Induced Breakdown Spectroscopy (LIBS)

Abe, Yuta; Otaka, Masahiko; Okazaki, Kodai*; Kawakami, Tomohiko*; Nakagiri, Toshio

Proceedings of 2019 International Congress on Advances in Nuclear Power Plants (ICAPP 2019) (Internet), 7 Pages, 2019/05

Since the hardness of fuel debris containing boride from B$$_{4}$$C pellet in control rod is estimated to be two times higher as that of oxide, such as UO$$_{2}$$ and ZrO$$_{2}$$, it is necessary to select the efficient and appropriate operation for removal of fuel debris formed in the severe accident of nuclear power plants. We focused on the characteristics of LIBS, an innovative rapid chemical in-situ analysis technology that enables simultaneous detection of B, O, and other metal elements in fuel debris. Simulated solidified melt specimens were obtained in the plasma heating tests (CMMR-0/-2, performed by JAEA) of simulated fuel assembly (ZrO$$_{2}$$ is used to simulated UO$$_{2}$$ pellet, other materials such as stainless steel, B$$_{4}$$C are same as fuel assembly). The LIBS signals of (B/O)/Zr ratio showed good linear relationship with Vickers hardness. This technique can be also applied as in-situ assessment tool for elemental composition and Vickers hardness of metal-oxide-boride materials.

Journal Articles

Profile monitor on target for spallation neutron source

Meigo, Shinichiro; Matsuda, Hiroki; Takei, Hayanori

Proceedings of 6th International Beam Instrumentation Conference (IBIC 2017) (Internet), p.373 - 376, 2018/03

no abstracts in English

Journal Articles

Degradation behavior of surface-mounted LED by $$gamma$$ irradiation

Takeuchi, Tomoaki; Otsuka, Noriaki; Uehara, Toshiaki; Kumahara, Hajime*; Tsuchiya, Kunihiko

QST-M-2; QST Takasaki Annual Report 2015, P. 80, 2017/03

no abstracts in English

Journal Articles

Chemical state analysis with soft-X-ray emission spectroscopy based on SEM

Terauchi, Masami*; Imazono, Takashi; Koike, Masato

Hyomen Kagaku, 36(4), p.184 - 188, 2015/04

Electron beam induced soft-X-ray emission spectroscopy (SXES) that uses a grating spectrometer has been introduced to a conventional scanning electron microscope (SEM) for characterizing desired specimen areas of bulk materials. The spectrometer has a grazing-incidence flat-field optics by using aberration corrected (varied-line-spacing) gratings, which has already been applied to transmission electron microscopes. The best resolution was confirmed as 0.13 eV at Mg L-emission (50 eV), which is comparable with that of recent dedicated electron energy-loss spectroscopy instruments. Apparent band structure effects have been observed in Mg-L, Si-L, B-K, and Ti-L emission spectra obtained from bulk materials using SEM-SXES instrument.

Journal Articles

Analysis of microscopic air-bone particle by combined system of in-air micro PIXE and ion luminescence microscopic imaging and spectroscopy

Kada, Wataru*; Yokoyama, Akihito; Sato, Takahiro; Koka, Masashi; Kamiya, Tomihiro

Hoshasen To Sangyo, (136), p.40 - 45, 2014/06

no abstracts in English

Journal Articles

Spectroscopic study of reaction mechanism of laser-ablated silicon ions and neutrals with benzene molecules

Saeki, Morihisa; Oba, Hironori; Yokoyama, Atsushi

Journal of Physics; Conference Series, 59, p.732 - 735, 2007/00

 Times Cited Count:0 Percentile:0(Optics)

We have performed laser ablation of silicon in neon gas and benzene vapor. The reaction mechanism of the ablated silicon atoms with the neon atoms and benzene molecules were investigated by space- and time-resolved emission spectroscopy. The ablation in the neon gas suggested that (1) the neutral neon atoms are excited to 2pn states lying in 18-19 eV and (2) the neutral neon atoms are excited by electronic-to-electronic and translational-to-electronic energy transfer from the silicon ions. In the ablation in the benzene vapor, we found that the benzene molecules are decomposed into C2 and CH radicals by the collision with the silicon atoms.

Journal Articles

Effect of thermal annealing on the photoluminescence from $$beta$$-FeSi$$_2$$ films on Si substrate

Yamaguchi, Kenji; Shimura, Kenichiro; Udono, Haruhiko*; Sasase, Masato*; Yamamoto, Hiroyuki; Shamoto, Shinichi; Hojo, Kiichi

Thin Solid Films, 508(1-2), p.367 - 370, 2006/06

 Times Cited Count:12 Percentile:49.71(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Characterization of photoluminescence of $$beta$$-FeSi$$_2$$ thin film fabricated on Si and SIMOX substrate by IBSD method

Shimura, Kenichiro; Yamaguchi, Kenji; Sasase, Masato*; Yamamoto, Hiroyuki; Shamoto, Shinichi; Hojo, Kiichi

Vacuum, 80(7), p.719 - 722, 2006/05

 Times Cited Count:9 Percentile:34.33(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Curium(III) species and the coordination states in concentrated LiCl-aqueous solutions studied by time-resolved laser-induced fluorescence spectroscopy

Arisaka, Makoto; Kimura, Takaumi; Nagaishi, Ryuji; Yoshida, Zenko

Journal of Alloys and Compounds, 408-412, p.1307 - 1311, 2006/02

 Times Cited Count:6 Percentile:42.74(Chemistry, Physical)

no abstracts in English

Journal Articles

Photoluminescence of $$beta$$-FeSi$$_2$$ thin film prepared by ion beam sputter deposition method

Shimura, Kenichiro; Yamaguchi, Kenji; Yamamoto, Hiroyuki; Sasase, Masato*; Shamoto, Shinichi; Hojo, Kiichi

Nuclear Instruments and Methods in Physics Research B, 242(1-2), p.673 - 675, 2006/01

 Times Cited Count:6 Percentile:43.85(Instruments & Instrumentation)

no abstracts in English

Journal Articles

Laser ablation of silicon in neon gas; Study of excitation mechanism of neon neutrals by ablated silicon ions

Saeki, Morihisa; Hirata, Koichi*; Sakka, Tetsuo*; Oba, Hironori; Yokoyama, Atsushi

Journal of Applied Physics, 98(4), p.044912_1 - 044912_6, 2005/08

 Times Cited Count:3 Percentile:13.7(Physics, Applied)

no abstracts in English

Journal Articles

Electronic structure of carbon nitride thin films studied by X-ray spectroscopy techniques

Hellgren, N.*; Guo, J.*; Luo, Y.*; S${aa}$the, C.*; Agui, Akane; Kashtanov, S.*; Nordgren, J.*; ${AA}$gren, H.*; Sundgren, J.-E.*

Thin Solid Films, 471(1-2), p.19 - 34, 2005/01

 Times Cited Count:133 Percentile:96.57(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Soft X-ray emission and absorption spectra of typical solid carbon compounds

Muramatsu, Yasuji; Gullikson, E. M.*; Perera, R. C. C.*

Advances in X-Ray Chemical Analysis, Japan, 35, p.125 - 136, 2004/00

Soft X-ray emission and absorption spectra in the CK region of typical solid carbon compounds (HOPG, carbon nanotube, diamond, fullerene, polyethylene, ${it p}$-terphenyl, anthracene) are demonstrated. Take-off/incident-angle dependent X-ray spectra of HOPG are also shown to utilize for the structural analysis of anistropic crystals. Spectral analysis of these compounds using discrete variational (DV)-X$$alpha$$ molecular orbital calclations is also demonstrated.

Journal Articles

Improvement of luminescence capability of Tb$$^{3+}$$-related emission by Al$$_{x}$$Ga$$_{1-x}$$N

Nakanishi, Yasuo*; Wakahara, Akihiro*; Okada, Hiroshi*; Yoshida, Akira*; Oshima, Takeshi; Ito, Hisayoshi

Physica Status Solidi (B), 240(2), p.372 - 375, 2003/11

 Times Cited Count:19 Percentile:65.58(Physics, Condensed Matter)

Luminescence propeties of Tb-doped Al$$_{x}$$Ga$$_{1-x}$$N were studied. The samples were grown on sapphire substrates using OMVPE. Tb implantation was cariied out to introduce Tb into samples. After implantation, samples were annealed at 1000 to 1150 $$^{o}$$C in 10% NH$$_{3}$$ diluted with N$$_{2}$$. The luminescence intensity for Al$$_{x}$$Ga$$_{1-x}$$N x=0.1 is 5 times stronger than that for x=0 at 14 K. The luminesecence intensity for GaN rapidly decreases with temperature and its activation enegy is 7.8 meV. With increasing Al content, the activation enegy increases, and the activation energy for Al$$_{0.1}$$Ga$$_{0.9}$$N is 70 meV.

Journal Articles

Effects of Al composition on luminescence properties of europium implanted Al$$_{x}$$Ga$$_{1-x}$$N(0$$<$$x$$<$$1)

Nakanishi, Yasuo*; Wakahara, Akihiro*; Okada, Hiroshi*; Yoshida, Akira*; Oshima, Takeshi; Ito, Hisayoshi; Shibata, Tomohiko*; Tanaka, Mitsuhiro*

Physica Status Solidi, 0(7), p.2623 - 2626, 2003/07

In our previous study, it was reported that Eu-doped Nitride semiconductors show luminescence propetires. In this study, we investigate the relationship between luminescence properties and Al composition using Al$$_{x}$$Ga$$_{1-x}$$N(0$$<$$x$$<$$1). Al$$_{x}$$Ga$$_{1-x}$$N were grown using OMVPE. Eu atoms were doped into the samples by ion implantation (200keV). After implantation, the samples were annealed to remove residual damege. Luminescence propreties of the samples were measured using photoluminescence and cathodeluminescence. As a result, luminescence at 621 nm which relates 4f-4f transition were observed for all samples (x=0 to 1). As for intensity, samples with x=0.5 show the strongest luminescence. This result can be interpreted in terms of the internal stress of crystals by the existence of Al atoms.

Journal Articles

Angle-resolved soft X-ray emission and absorption spectroscopy of hexagonal boron nitride

Muramatsu, Yasuji; Kaneyoshi, Takahiro*; Gullikson, E. M.*; Perera, R. C. C.*

Spectrochimica Acta, Part A, 59(9), p.1951 - 1957, 2003/07

Angle-resolved soft X-ray emission and absorption spectra in the BK and NK regions of hexagonal BN were measured using polarized synchrotron radiation. The take-off/incident-angle-dependence on the spectral features in both X-ray emission and absorption is clearly observed. The configuration of the s and p orbitals, which were calculated using discrete variaional (DV) -Xa molecular orbital calculations, explains the angle-resolved soft X-ray emission and absorption spectra. The relative peak intensity of the 394-eV peak in the NK X-ray emission provides useful information about the BN layer ordering.

Journal Articles

The Development of image analysis type emittance monitor

Chiba, Atsuya; Ishii, Yasuyuki; Tajima, Satoshi

Dai-15-Kai Tandemu Kasokuki Oyobi Sono Shuhen Gijutsu No Kenkyukai Hokokushu, p.74 - 76, 2003/03

no abstracts in English

Journal Articles

Positronium formation at low temperatures; The Role of trapped electrons

Hirade, Tetsuya

Hoshasen Kagaku, (75), p.46 - 51, 2003/03

Enhancement of positronium (Ps) formation at low temperatures has been observed in many materials since 1980's. There were some interpretations. However, none of them explained the phenomena successfully. In 1998, a new idea of the Ps formation was proposed and the expected phenomena were successfully observed. This new Ps formation process will be explained with those experimental results and the possibility of usage of Ps formation for radiation chemistry researches will be also discussed.

164 (Records 1-20 displayed on this page)